Fluid generation and evolution during exhumation of deeply subducted UHP continental crust: Petrogenesis of composite granite–quartz veins in the Sulu belt,China          下载免费PDF全文

S.‐J. Wang  L. Wang  M. Brown  P. M. Piccoli  T. E. Johnson  P. Feng  H. Deng  K. Kitajima  Y. Huang 《Journal of Metamorphic Geology》2017,35(6):601-629

Composite granite–quartz veins occur in retrogressed ultrahigh pressure (UHP) eclogite enclosed in gneiss at General's Hill in the central Sulu belt, eastern China. The granite in the veins has a high‐pressure (HP) mineral assemblage of dominantly quartz+phengite+allanite/epidote+garnet that yields pressures of 2.5–2.1 GPa (Si‐in‐phengite barometry) and temperatures of 850–780°C (Ti‐in‐zircon thermometry) at 2.5 GPa (~20°C lower at 2.1 GPa). Zircon overgrowths on inherited cores and new grains of zircon from both components of the composite veins crystallized at c. 221 Ma. This age overlaps the timing of HP retrograde recrystallization dated at 225–215 Ma from multiple localities in the Sulu belt, consistent with the HP conditions retrieved from the granite. The ε_Hf(t) values of new zircon from both components of the composite veins and the Sr–Nd isotope compositions of the granite consistently lie between values for gneiss and eclogite, whereas δ¹⁸O values of new zircon are similar in the veins and the crustal rocks. These data are consistent with zircon growth from a blended fluid generated internally within the gneiss and the eclogite, without any ingress of fluid from an external source. However, at the peak metamorphic pressure, which could have reached 7 GPa, the rocks were likely fluid absent. During initial exhumation under UHP conditions, exsolution of H₂O from nominally anhydrous minerals generated a grain boundary supercritical fluid in both gneiss and eclogite. As exhumation progressed, the volume of fluid increased allowing it to migrate by diffusing porous flow from grain boundaries into channels and drain from the dominant gneiss through the subordinate eclogite. This produced a blended fluid intermediate in its isotope composition between the two end‐members, as recorded by the composite veins. During exhumation from UHP (coesite) eclogite to HP (quartz) eclogite facies conditions, the supercritical fluid evolved by dissolution of the silicate mineral matrix, becoming increasingly solute‐rich, more ‘granitic’ and more viscous until it became trapped. As crystallization began by diffusive loss of H₂O to the host eclogite concomitant with ongoing exhumation of the crust, the trapped supercritical fluid intersected the solvus for the granite–H₂O system, allowing phase separation and formation of the composite granite–quartz veins. Subsequently, during the transition from HP eclogite to amphibolite facies conditions, minor phengite breakdown melting is recorded in both the granite and the gneiss by K‐feldspar+plagioclase+biotite aggregates located around phengite and by K‐feldspar veinlets along grain boundaries. Phase equilibria modelling of the granite indicates that this late‐stage melting records P–T conditions towards the end of the exhumation, with the subsolidus assemblage yielding 0.7–1.1 GPa at <670°C. Thus, the composite granite–quartz veins represent a rare example of a natural system recording how the fluid phase evolved during exhumation of continental crust. The successive availability of different fluid phases attending retrograde metamorphism from UHP eclogite to amphibolite facies conditions will affect the transport of trace elements through the continental crust and the role of these fluids as metasomatic agents interacting with the mantle wedge in the subduction channel.  相似文献   

Dating the onset of Lower Tagus River terrace formation using electron spin resonance          下载免费PDF全文

PIERLUIGI ROSINA  PIERRE VOINCHET  JEAN‐JACQUES BAHAIN  JORGE CRISTOVÃO  CHRISTOPHE FALGUÈRES 《第四纪科学杂志》2014,29(2):153-162

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Middle to early Late Ordovician hydrothermal veining in the Molong Volcanic Belt,northeastern Lachlan Fold Belt: Sedimentological evidence     

G. H. Packham  J. B. Keene  L. M. Barron 《Australian Journal of Earth Sciences》2013,60(2):257-269

Detrital volcanic and vein quartz, accompanied by felsic volcanic debris, occur as minor constituents in the Ordovician subduction‐related mafic volcanics of the Molong Volcanic Belt. In the western province of the Molong Volcanic Belt, detrital quartz is present in the three episodes of the mafic Volcanics. Volcanic quartz occurs in allochthonous limestone blocks in the Bendigonian Hensleigh Siltstone overlying the Mitchell Formation. The second volcanic episode (the Fairbridge Volcanics) commenced after a hiatus of approximately 20 million years and lasted around 10 million years from Darriwilian to Gisbornian time. Locally derived vein quartz, volcanic quartz and felsic detritus are concentrated at the bases of autochthonous Wahringa and Yuranigh Limestone Members of the volcanics and are extensive and abundant in basal beds of the regional Eastonian limestone body that transgressed over an eroded volcanic centre at Cargo. This early Eastonian debris, deposited early in an 8 million‐year volcanic hiatus preceding the final Ordovician Bolindian volcanism, establishes a pre‐Eastonian age for mineralisation at Cargo. It is inferred that the pauses in volcanism were preceded by magmatic fractionation, intrusion and hydrothermal activity and followed by erosion, subsidence and deposition of autochthonous limestones. Minor occurrences of vein and volcanic quartz are found in Bolindian volcanogenic sediments of the third volcanic phase. It is concluded that hydrothermal vein formation (and mineralisation by inference) was associated with pauses in volcanic activity throughout the Middle to early Late Ordovician over a wide area in the western province, culminating in the mineralisation at Cargo and Copper Hill near Molong. Volcanism in the eastern province of the Molong Volcanic Belt was continuous from at least Darriwilian to latest Ordovician time. Here, detrital hydrothermal vein quartz and volcanic quartz and felsic detritus are distributed through late Middle and early Late Ordovician turbidites of the Weemalla Formation. The possible existence of cycles in the source area like those of the Fairbridge Volcanics is masked by the distal nature of these deposits. Vein formation occurred in both provinces from late Middle Ordovician to early Late Ordovician, long before the formation of the world‐class mineral deposit at Cadia associated with the latest Ordovician Cadia Monzonite.  相似文献   

海洋沉积物中石英单矿物的化学分离   总被引：7，自引：1，他引：7  

万世明  蒋恒毅  李安春 《海洋地质与第四纪地质》2003,23(3):123-128

海洋沉积物中的石英作为陆源物质的标志性矿物,是古环境和古气候演化的信息载体,已成为古环境和古气候演化研究的重要替代指标.提供了改进了的化学分离海洋沉积物中石英单矿物的方法流程.在流程中的不同阶段可有效去掉全样中的生物组分、粘土矿物和长石等,取得海洋沉积物全样的总陆源矿物、石英+长石、石英的相对和绝对含量,通过计算可获得各种组分的通量,通过粒度分析可获得粒度数据.同一样品的17次重复实验表明,含量结果的平均相对误差仅为2.36%;显微镜和X射线衍射分析检查所分离出的石英纯度可达98%以上;激光粒度分析表明,化学试剂对石英的溶蚀作用不明显,不影响粒度分析结果.  相似文献   

大兴安岭扎兰屯地区晚奥陶世石英闪长岩体岩石地球化学特征及其地质意义   总被引：2，自引：0，他引：2  

马庆  刘建峰  迟效国 《地质通报》2018,37(5):853-862

扎兰屯音河岩体被音河水系分为南、北两部分,研究发现南、北岩体形成年代不同,选取南部岩体(称为二村岩体)进行研究。二村岩体主要由石英闪长岩-英云闪长岩组成,石英闪长岩的LA-ICP-MS锆石U-Pb年龄为444.0±4.6Ma,时代为晚奥陶世。岩石化学组成相对富钠、贫钾,Na2O/K2O值大于1(1.73~3.17),属中钾钙碱性系列。岩石富含轻稀土元素、亏损重稀土元素,富集大离子亲石元素Rb、Ba、K,显著亏损Nb、Ta、P、Ti等高场强元素。矿物组成及岩石地球化学特征指示其为I型花岗岩。岩体的形成时代、构造背景与多宝山岛弧火成岩相似,为区域多宝山岛弧西南向延伸提供了新的制约。  相似文献   

Ore-bearing fluids of the Eldorado gold deposit (Yenisei Ridge,Russia)     

N.A. Gibsher  A.A. Tomilenko  A.M. Sazonov  T.A. Bul’bak  M.O. Khomenko  M.A. Ryabukha  E.O. Shaparenko  S.A. Sil’yanov  N.A. Nekrasova 《Russian Geology and Geophysics》2018,59(8):983-996

The Eldorado low-sulfide gold-quartz deposit, with gold reserves of more than 60 tons, is located in the damage zone of the Ishimba Fault in the Yenisei Ridge and is hosted by Riphean epidote-amphibolite metamorphic rocks (Sukhoi Pit Group). Orebodies occur in four roughly parallel heavily fractured zones where rocks were subject to metamorphism under stress and heat impacts. They consist of sulfide-bearing schists with veins of gray or milky-white quartz varieties. Gray quartz predominating in gold-bearing orebodies contains graphite and amorphous carbon identified by Raman spectroscopy; the contents of gold and amorphous carbon are in positive correlation. As inferred from thermobarometry, gas chromatography, gas chromatography-mass spectrometry, and Raman spectroscopy of fluid inclusions in sulfides, carbonates, and gray and white quartz, gold mineralization formed under the effect of reduced H₂O-CO₂-HC fluids with temperatures of 180 to 490 °C, salinity of 9 to 22 wt.% NaCl equiv, and pressures of 0.1 to 2.3 kbar. Judging by the presence of 11% mantle helium (³He) in fluid inclusions from quartz and the sulfur isotope composition (7.1-17.4‰ δ³⁴S) of sulfides, ore-bearing fluids ascended from a mantle source along shear zones, where they “boiled”. While the fluids were ascending, the metalliferous S- and N-bearing hydrocarbon (HC) compounds they carried broke down to produce crystalline sulfides, gold, and disseminated graphite and amorphous carbon (the latter imparts the gray color to quartz). Barren veins of milky-white quartz formed from oxidized mainly aqueous fluids with a salinity of < 15 wt.% NaCl equiv at 150-350 °C. Chloride brines (> 30 wt.% NaCl equiv) at 150-260 °C impregnated the gold-bearing quartz veins and produced the lower strata of the hydrothermal-granitoid section. The gold mineralization (795-710 Ma) was roughly coeval to local high-temperature stress metamorphism (836-745 Ma) and intrusion of the Kalama multiphase complex (880-752 Ma).  相似文献   

Fluid Inclusion Studies of Comb Quartz and Stibnite at the Hishikari Au–Ag Epithermal Deposit,Japan     

《Resource Geology》2018,68(3):326-335

Fluid inclusion microthermometry was conducted on late‐stage barren comb quartz and the latest stibnite at the Hishikari deposit to characterize the hydrothermal activity responsible for vein formation. Eight fluid inclusion assemblages (i.e. fluid inclusions trapped at the same time, ‘FIAs’) were studied to determine the formation fluid temperatures and salinities for the comb quartz in the Shosen No. 2 vein, Sanjin ore zone, and the stibnite in the Seisen No. 1–1 vein, Yamada ore zone. The average homogenization temperatures (the formation temperatures) of the seven FIAs from the comb quartz were between 207 and 230°C, while the average homogenization temperature (the formation temperature) of an FIA from the stibnite was 113°C. The measured fluid salinities of the seven FIAs from the comb quartz were low, ranging between 0.0 and 1.1 wt% NaCl equiv., indicating that dilute fluids were responsible for the comb quartz formation. By comparison with previous microthermometric data, the formation temperatures of the studied comb quartz were higher than those of columnar adularia and comb quartz at most other veins (generally around 200°C) but were similar to those of columnar adularia at Keisen veins (230°C) in the same ore zone. The higher formation temperatures both in the Shosen and the Keisen veins in the Sanjin ore zone indicate that the fractures corresponding to the vein system at the Sanjin ore zone were main conduits for hot ascending fluids. The low formation temperature of stibnite in the latest stage (113°C) indicates that stibnite precipitation occurred during a waning stage of hydrothermal activity. Combined with previous thermodynamic data on antimony solubilities, the large discrepancy between the formation temperature of the comb quartz (200–230°C) and that of the stibnite suggests that the stibnite may have precipitated as a result of a drastic cooling of the hydrothermal system.  相似文献   

皖南东至兆吉口铅锌矿床成矿时代的厘定及其找矿指示意义   总被引：1，自引：0，他引：1  

傅仲阳  徐晓春  刘晓燕  刘雪  谢巧勤 《矿床地质》2018,37(3):463-480

皖南东至兆吉口铅锌矿床是近年来在江南过渡带西段新发现的一个规模达中型的中-低温热液型矿床。目前揭露的铅锌矿体均赋存于东至断裂带及其西侧次级张(扭)性断裂及裂隙中。文章选取了该矿床主要矿石矿物闪锌矿以及与主成矿阶段金属硫化物紧密共生的石英,分别采用流体包裹体Rb-Sr法和40Ar-39Ar法进行同位素地质年龄测定。4件闪锌矿样品获得流体包裹体Rb-Sr等时线年龄为(128±1)Ma;2件石英样品获得流体包裹体40Ar-39Ar坪年龄分别为(128.74±3.02)Ma和(128.19±1.98)Ma,等时线年龄分别为(128.81±5.25)Ma和(128.30±3.47)Ma,反等时线年龄分别为(128.82±5.24)Ma和(128.31±3.47)Ma。同位素地质年龄测试结果基本一致,表明兆吉口铅锌矿床形成于128 Ma左右,成矿时代为早白垩世。该成矿年龄与赋矿闪长玢岩的形成时间((129.0±2.3)Ma~(128.4±2.7)Ma)一致,也与东至断裂燕山晚期的活动年龄((126.3±2.2)Ma)相近,表明该矿床成矿与燕山晚期的构造-岩浆活动密切相关,此时区域构造背景为强烈挤压后的伸展环境。这一矿化事件在成矿时代上明显晚于长江中下游成矿带中的断隆区(如铜陵、安庆-贵池等矿集区)的铜金多金属矿床和皖南成矿带中的钨钼多金属矿床(136 Ma),而与长江中下游成矿带断坳区的玢岩铁矿床的成矿时间(135~127 Ma)相近,指示长江中下游成矿带与皖南成矿带之间的江南过渡带中发育有燕山晚期较晚阶段(128 Ma左右)的铅锌矿化事件,为今后在该区开展铅锌多金属矿床找矿勘探提供了重要依据。  相似文献   

粉色水晶内针状包裹体的成分与分布特征研究   总被引：1，自引：1，他引：0  

胡哲  郭颖 《岩矿测试》2018,37(3):306-312

粉色水晶内部的针状包裹体常被认为是三组呈三方对称的金红石或蓝线石,至今未有定论。本文选取含有针状包裹体的4颗星光粉晶,利用宝石学显微镜、激光拉曼光谱仪及紫外可见分光光度计对样品进行观察与测试,以确定包裹体的分布特征及矿物种类。无损拉曼测试发现包裹体的特征振动峰949 cm-1、999 cm-1与蓝线石标准峰相匹配,可确定针状包裹体为蓝线石或与其极为相近的矿物。放大检查发现,包裹体直径约0.5μm,长度可达毫米级,近定向分布,整体上呈汇聚状,在某些位置可粗略分为三组,同组针状包裹体近似平行分布。造成六射星光的三组蓝线石立体相交,未观察到明显的三方对称关系,与水晶的结晶习性无直接关系,故认为蓝线石为先成包裹体,在水晶的生长过程中被捕获。紫外可见分光光谱仅显示粉色蓝线石的特征吸收,表明大量的粉色蓝线石包裹体对粉色水晶的粉色有一定贡献。  相似文献   

西藏西北部浅变质石英砂岩岩石学特征及其构造意义   总被引：1，自引：0，他引：1  

伍连东  苑婷媛  金海龙  刘焰 《岩石学报》2018,34(3):701-718

羌塘盆地中央隆起带主要由浅变质石英砂岩组成,由于化石匮乏、变形强烈,长期以来对这套浅变质石英砂岩成因的争议颇大,导致了对藏西北地区前中生代构造演化的认识长期模糊不清,其中,何处才是冈瓦纳大陆北界就是一个长期争论的议题。在西藏西北部,近东西走向的布尔嘎错断裂带将北部的查多岗日地块与南部的南羌塘地块分隔开,浅变质石英砂岩广泛出露于这两地块之内。沿近东西走向布尔嘎错断裂带断续产出的冈玛错蓝片岩、蛇绿岩等岩片大体呈南北向逆冲于浅变质石英砂岩之上,因此早期曾认为布尔嘎错断裂带是冈瓦纳大陆之北界。本文的调查与研究发现查多岗日和南羌塘地块内浅变质石英砂岩岩相学特征完全相同,均主要由石英组成,遭受了绿片岩相的变质作用,形成了钠长石+绿泥石+白云母组合,充填于早期石英颗粒之间,钠长石交代钾长石。这两地的浅变质石英砂岩均被未变质钙质胶结的钾长石石英砂岩平行不整合覆盖。碎屑锆石的阴极发光分析与U-Pb定年结果进一步证实了查多岗日与南羌塘地块内浅变质石英砂岩内的锆石来源完全相同。这些证据充分反映了查多岗日与南羌塘地块早期构造演化过程相似,源自同一大陆。碎屑锆石定年结果进一步表明浅变质石英砂岩的最大沉积年龄为520±8Ma,该岩石再被约480Ma的花岗岩脉侵入,因此其很可能形成于晚寒武世,而不整合面之上沉积岩的最大沉积年龄为460±8Ma,表明该不整合面上、下沉积岩之间存在明显的沉积间断,证实了该平行不整合面形成于奥陶纪。不整合面之下的浅变质石英砂岩因此与杨耀等(2014)报道的荣玛组相同,不整合面之上未变质长石石英砂岩则属于中上奥陶统塔石山组。查多岗日地块因此是西藏境内最北端的冈瓦纳大陆的碎块。在西藏西北部,冈瓦纳大陆北界为龙木错-帮达错-(83°40'E、35°N)-红脊山-荣玛乡。布尔嘎错断裂带不是冈瓦纳大陆之北界。  相似文献